Metals from space
Iron meteorites are natural alloys of iron and nickel. Their structure, strength and crystal patterns show metallic bonding and slow cooling on a scale no laboratory can match.
- Explain the properties of metals and alloys using metallic bonding.
- Explain how Widmanstätten patterns form.
- Calculate a density in kg/m³ from measurements in g and cm³.
Links to: GCSE chemistry, bonding and properties of matter: metallic bonding, metals and alloys; physics: density; maths: unit conversion.
Metallic bonding
In a metal, positive ions are arranged in a regular lattice surrounded by a 'sea' of delocalised electrons. The strong attraction between ions and electrons gives metals high melting points. The electrons can move, so metals conduct electricity and heat. Layers of ions can slide, so pure metals are malleable.
In an alloy, atoms of different sizes distort the layers, making it harder for them to slide. Alloys are therefore usually harder than pure metals. Meteoritic iron, an alloy containing nickel, is tough enough that it was hammered into tools, beads and blades thousands of years before people could smelt iron.
Patterns from slow cooling
Iron-nickel metal can exist in two crystal forms: taenite, which is richer in nickel, and kamacite, which has less nickel. In an asteroid's core, the metal crystallised as taenite. As the core cooled, kamacite slowly grew as plates inside it, along particular directions in the crystal.
When a slice of an iron meteorite is polished and lightly etched with dilute acid in a laboratory, these plates show up as a criss-cross of bands called the Widmanstätten pattern. It only forms with extremely slow cooling, from a few to thousands of degrees per million years, impossible to reproduce in a factory. A Widmanstätten pattern is therefore strong evidence of a meteorite.
Weathering
Iron-nickel metal rusts. Iron meteorites that land in damp places slowly oxidise, and chlorine from the soil speeds the process up. Museums store them in dry conditions to stop them crumbling.
Density in SI units
A slice of iron meteorite has a mass of 312 g and a volume of 40 cm³. Calculate its density in g/cm³ and in kg/m³.
- density = mass ÷ volume = 312 ÷ 40 = 7.8 g/cm³.
- 1 g/cm³ = 1,000 kg/m³, because 1 kg = 1,000 g and 1 m³ = 1,000,000 cm³.
- 7.8 g/cm³ × 1,000 = 7,800 kg/m³.
Answer: 7.8 g/cm³, which is 7,800 kg/m³, typical of iron-nickel metal and about three times the density of most rocks.
Draw labelled diagrams of the particles in a pure metal and in an alloy. Use them to explain why the iron-nickel alloy of a meteorite is harder than pure iron. Then explain, in three steps, why finding a Widmanstätten pattern in a lump of metal suggests it came from an asteroid's core.
Quiz
5 questions. Choose an answer to see whether you are right and why. Finish the quiz to complete the lesson.
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Question 1Why do metals conduct electricity?
The sea of delocalised electrons can flow through the lattice, carrying charge.
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Question 2Why are alloys usually harder than pure metals?
Distorted layers resist sliding, making the alloy harder.
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Question 3What are the two iron-nickel minerals in a Widmanstätten pattern?
Plates of kamacite grow within taenite as the metal slowly cools.
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Question 4Why can't Widmanstätten patterns be made in factories?
The pattern grows only with extremely slow cooling, from a few to thousands of degrees per million years.
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Question 5Convert 3.5 g/cm³ to kg/m³.
Multiply by 1,000: 3.5 g/cm³ = 3,500 kg/m³.